Energetics and Electronic Properties of Interstitial Chlorine in CdTe

Indexación: Scopus.We acknowledge support from Chilean funding agency FONDECYT under Grants No. 1170480 (W.O.) and 1171807 (E.M-P.). Powered@NLHPC: This research was partially supported by the supercomputing infrastructure of the NLHPC (ECM-02).The role of interstitial chlorine in the electronic properties of CdTe is addressed by density functional theory calculations including hybrid functionals and large unit cells. The stability and diffusion energy barriers of the impurity are analyzed as a function of the Fermi level position in the band gap. Chlorine is found to be stable in at least five interstitial sites with rather close formation energies, suggesting that they are all probable to be found. In p-type CdTe, the most stable sites are at the center of a CdTe bond and at a split-interstitial configuration, both acting as shallow donors. Whereas in n-type CdTe, it is found at the tetrahedral site surrounded by Cd hosts, acting as a shallow acceptor. We also find that chlorine can induce a deep acceptor level in the bandgap after binding with three Cd host atoms, which can explain the experimentally observed high resistivity in Cl-doped CdTe. The energy barriers for chlorine diffusion in both p-type and n-type CdTe are also discussed. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheimhttps://onlinelibrary.wiley.com/doi/full/10.1002/pssb.20180021

Field ionization electrodes Patent

Electrodes having array of small surfaces for field ionizatio

Racial categories in machine learning

Controversies around race and machine learning have sparked debate among computer scientists over how to design machine learning systems that guarantee fairness. These debates rarely engage with how racial identity is embedded in our social experience, making for sociological and psychological complexity. This complexity challenges the paradigm of considering fairness to be a formal property of supervised learning with respect to protected personal attributes. Racial identity is not simply a personal subjective quality. For people labeled "Black" it is an ascribed political category that has consequences for social differentiation embedded in systemic patterns of social inequality achieved through both social and spatial segregation. In the United States, racial classification can best be understood as a system of inherently unequal status categories that places whites as the most privileged category while signifying the Negro/black category as stigmatized. Social stigma is reinforced through the unequal distribution of societal rewards and goods along racial lines that is reinforced by state, corporate, and civic institutions and practices. This creates a dilemma for society and designers: be blind to racial group disparities and thereby reify racialized social inequality by no longer measuring systemic inequality, or be conscious of racial categories in a way that itself reifies race. We propose a third option. By preceding group fairness interventions with unsupervised learning to dynamically detect patterns of segregation, machine learning systems can mitigate the root cause of social disparities, social segregation and stratification, without further anchoring status categories of disadvantage

Renormalized coordinate approach to the thermalization process

We consider a particle in the harmonic approximation coupled linearly to an environment. modeled by an infinite set of harmonic oscillators. The system (particle--environment) is considered in a cavity at thermal equilibrium. We employ the recently introduced notion of renormalized coordinates to investigate the time evolution of the particle occupation number. For comparison we first present this study in bare coordinates. For a long ellapsed time, in both approaches, the occupation number of the particle becomes independent of its initial value. The value of ocupation number of the particle is the physically expected one at the given temperature. So we have a Markovian process, describing the particle thermalization with the environment. With renormalized coordinates no renormalization procedure is required, leading directly to a finite result.Comment: 16 pages, LATEX, 2 figure

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Soil quality and farm profitability: A win-win situation

Farmers are more likely to adopt and adapt improved soil management strategies if their efforts lead to an immediate economic benefit. An encouraging policy environment, as well as farmer organisation also stimulates the adoption of conservation practices. In Mexico, farmers are adapting their maize-based cropping systems to conservation agriculture, leading to both higher profits and soil conservation

Quantum capacitor with discrete charge-anticharge: spectrum and forces

The quantum capacitor with discrete charge is modeled by a Hamiltonian containing an inductive intrinsic term (tunnel effect between plates). The spectrum is obtained using a double Hilbert space. Fluctuations in the charge-anticharge pairs (zero total charge) give rise to an elementary attraction which is compared to the Casimir force. In this case, the field-fluctuations force could be also interpreted as charge-fluctuations force

The distribution of oxygen at the Ni81Fe19/Ta interface

The knowledge of how oxygen atoms are distributed at a magnetic-metal / oxide, or magnetic-metal / non-magnetic-metal interface, can be an useful tool to optimize device production. Multilayered Ni81Fe19 / Ta samples consisting of 15 bilayers of 2.5 nm each, grown onto glass substrates by magnetron sputtering from Ni81Fe19 and Ta targets, have been investigated. X-ray absorption near edge structure, extended X-Ray absorption fine structure, small angle X-ray diffraction, and simulations, were used to characterize the samples. Oxygen atoms incorporated onto Ni81Fe19 films during O2 exposition are mainly bonded to Fe atoms. This partial oxidation of the Ni81Fe19 surface works as a barrier to arriving Ta atoms, preventing intermixing at the Ni81Fe19 / Ta interface. The reduction of the Ni81Fe19 surface by the formation of TaO x is observed.Comment: 14 pages, 9 figures, accepted for publication in Advances in Materials Science and Engineerin